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Perfume

Perfume is a mixture of fragrant essential oils and aroma compounds, fixatives, and solvents used to give the human body, objects, and living spaces a pleasant smell. The amount and type of solvent mix with the fragrance oil dictates whether a perfume is considered a perfume extract, Eau de parfum, Eau de toilette, or Eau de Cologne.

Perfume:Bottles of some notable commercial perfumes: (clockwise from top left) Bois De Violette, Serge Lutens, 1992; Angel, Thierry Mugler, 1994; Shalimar, Guerlain, 1925; Beyond Paradise, Estée Lauder, 2003; No. 5, Chanel, 1921 (Pre-1950 bottle); Cabochard, Parfums Grès, 1959 (original bottle); Bellodgia, Caron, 1927; Arpège, Lanvin, 1927 (original bottle); Nombre Noir, Shiseido, 1981; Mitsouko, Guerlain, 1919; Pour Un Homme, Caron, 1934.
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Bottles of some notable commercial perfumes: (clockwise from top left) Bois De Violette, Serge Lutens, 1992; Angel, Thierry Mugler, 1994; Shalimar, Guerlain, 1925; Beyond Paradise, Estée Lauder, 2003; No. 5, Chanel, 1921 (Pre-1950 bottle); Cabochard, Parfums Grès, 1959 (original bottle); Bellodgia, Caron, 1927; Arpège, Lanvin, 1927 (original bottle); Nombre Noir, Shiseido, 1981; Mitsouko, Guerlain, 1919; Pour Un Homme, Caron, 1934.

Contents

Description of a perfume

Perfume:Shelves of perfumes
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Shelves of perfumes

It is impossible to describe a perfume according to its components because the formulas are kept secret. Even if the formulas are known, the ingredients are often too numerous to provide a useful classification. Cognoscenti can, however, generally get a handle on the principal ingredients. On the other hand, it is possible to group perfumes into olfactive families and describe them through the notes that appear as they slowly evaporate. Perfumes can also be classified according to their concentration. [1][2][3]

Olfactive families

Fragrances can be classified into several olfactive families, by the themes, or accords, of these fragrances.

Fragrance notes

A mixture of alcohol and water is used as the solvent for the aromatics. On application, body heat causes the solvent to quickly disperse, leaving the fragrance to evaporate gradually over several hours. The rate of evaporation (vapor pressure) and the odor strength of the compound partly determine the tenacity of the compound and determine its perfume note classification.

Concentration and composition

Perfumes oils, or the "juice" of perfume composition, are diluted with a suitable solvent to make the perfume more usable. This is done because undiluted oils (natural or synthetic) contain high concentrations of volatile components that will likely result in allergic reactions and possibly injury when applied directly to skin or clothing.

Although dilutions of the perfume oil can be done using solvents such as jojoba, fractionated coconut oil, and wax, the most common solvents for perfume oil dilution is ethanol or a mixture of ethanol and water. The percent of perfume oil by volume in a perfume is listed as follows:

As the percentage of aromatic compounds decreases, the intensity and longevity of the scent decrease. It should be noted that different perfumeries or perfume houses assign different amounts of oils to each of their perfumes. As such, although the oil concentration of a perfume in eau de parfum (EDP) dilution will necessarily be higher than the same perfume in eau de toilette (EDT) form, the same trends may not necessarily apply to different perfume compositions much less across different perfume houses.

Furthermore, some fragrances with the same product name but having a different concentration name may not only differ in their dillutions, but actually use different perfume oil mixtures altogether. For instance, in order to make the EDT version of a fragrance brighter and fresher than its EDP, the EDT oil may be "tweaked" to contain slightly more top notes or less base notes. In some cases, words such as "extrême" or "concentrée" appended to frangrance names might indicate completely different frangrances that relates only because of a similar perfume accord. An instance to this would be Chanel‘s Pour Monsieur and Pour Monsieur Concentrée.

Natural and synthetic aromatics

Plant sources

Plants have long been used in perfumery as a source of essential oils and aroma compounds. These aromatics are usually secondary metabolites produced by plants as protection against herbivores, infections, as well as to attract pollinators. Plants are by far the largest source of fragrant compounds used in perfumery. The sources of these compounds may be derived from various parts of a plant. A plant can offer more than one source of aromatics, for instance the aerial portions and seeds of coriander have remarkably different odors from each other. Orange leaves, blossoms, and fruit zest are the respective sources of petit grain, neroli, and orange oils.

Animal sources

Synthetic sources

Synthetic aromatics are created through organic synthesis from various chemical compounds that are obtained from petroleum distillates, pine resins, or other relatively cheap organic feedstock. Synthetics can provide fragrances which are not found in nature. For instance, Calone, a compound of synthetic origin, imparts a fresh ozonous metallic marine scent that is widely used in contemporary perfumes. Synthetic aromatics are often used as an alternate source of compounds that are not easily obtained from natural sources. For example, linalool and coumarin are both naturally occurring compounds that can be cheaply synthesized from terpenes. Orchid scents (typically salicylates) are usually not obtained directly from the plant itself but are instead synthetically created to match the fragrant compounds found in various orchids.

The majority of the world's synthetic aromatics are created by relatively few companies. They include:

Each of these companies patent several processes for the production of aromatic synthetics annually.

See Aroma compound

Obtaining natural odorants

Before perfumes can be composed, the odorants used in various perfume compositions must first be obtained. Synthetic odorants are produced through organic synthesis and purified. Odorants from natural sources require the use of various methods to extract the aromatics from the raw materials. The results of the extraction are either essential oils, absolutes, concretes, or butters, depending on the amount of waxes in the extracted product. [4]

All these techniques will to a certain extent, distort the odour of the aromatic compounds obtained from the raw materials. This is due to the use of heat, harsh solvents, or through exposure to oxygen in the extraction process which will denature the aromatic compounds, which either change their odour character or renders them odourless.

Fragrant extracts

Although fragrant extracts are known to the general public as the generic term "essential oils", a more specific language is used in the fragrance industry to describe the source, purity, and technique used to obtain a particular fragrant extract.

Of these extracts, only absolutes, essential oils, and tinctures are directly used to formulate perfumes.

Composing perfumes

Perfume compositions are an important part of many industries ranging from the luxury goods sectors, food services industries, to manufacturers of various household chemicals. The purpose of using perfume or fragrance compositions in these industries is to affect customers through their sense of smell and entice them into purchasing the perfume or perfumed product. As such there is significant interest in producing a perfume formulation that people will find aesthetically pleasing.

The Perfumer

The job of composing perfumes that will sell is left up to an expert on perfume composition or known in the fragrance industry as the perfumer. They are also sometimes referred to affectionately as "the Nose" due to their fine sense of smell and skill in smell composition. The perfumer is effectively an artist who is trained in depth on the concepts of fragrance aesthetics and who is capable of conveying abstract concepts and moods with their fragrance compositions. At the most rudimentary level, a perfumer must not only have a keen knowledge of a large variety of fragrance ingredients and their smells, and be able to distinguish each of the fragrance ingredients whether alone or in combination with other frangrances. As well, they must know how each ingredient reveals itself through time with other ingredients. The job of the perfumer is very similar to that of flavourists, who compose smells and flavourants for many commercial food products.

The composition of a perfume typically begins with a brief by the perfumer's employer or an outside customer. The customers to the perfumer or their employers, are typically fashion houses or large corporations of various industries. Each brief will contain the specifications for the desired perfume, and will describe in often poetic or abstract terms what the perfume should smell like or what feelings it should evoke in those who smell it, along with a maximum per litre price of the perfume oil concentrate. This allowance, along with the intended application of the perfume will determine what aromatics and fragrance ingrediants can/will be used in the perfume composition.

The perfumer will then go through the process of blending multiple perfume mixtures and will attempt to capture the desired feelings specified in the brief. After presenting the perfume mixtures to the customers, the perfumer may "win" the brief with their approval, and proceed to sell the formulation to the customer, often with modifications of the composition of the perfume. This process typically spans over several months to several years. The perfume composition will then be either used to enhance another product as a functional fragrance (shampoos, make-up, detergents, car interiors, etc.), or marketed and sold directly to the public as a fine fragrance.

Alternatively, the perfumer may simply be inspired to create a perfume and produce something that later becomes marketable or successfully wins a brief. This usually happens in smaller or independent perfume houses.[1]

Technique

Perfume oils usually contain tens to hundreds of ingredients. Included in the perfume are fixatives, which bind the various fragrances together, such as balsams, ambergris, and secretions from the scent glands of the civet cat and musk deer (undiluted, these have unpleasant smells but in alcoholic solution they act as preserving agents). The mixture is normally aged for one year.Animal products have not been used in the development of perfumes for decades but the old techniques are what people seem to remember. Most modern perfumes and colognes are made using the fragrance oils that the fragrances houses develop using essential oils and aromatic chemicals. The fragrance oils are then blended with alcohol and water, aged in tanks for a minimum of 14 days and filtered through processing equipment to remove any sediment and particles before the solution can be filled into the perfume bottles. Delbia Do Company(NYC)is one manufacturer of luxury niche perfumes that has a permit from the BATF(TTB) to manufacture perfumes / colognes using ethyl alcohol as well as being registered with the FDA as a manufacturer of Cosmetics.

Reverse engineering

Creating perfumes through reverse engineering with analytical techniques such as GC/MS can reveal some of the formula for a particular perfume but most perfumes are difficult to analyze because of their complexity, particularly due to presence of essential oils and other ingredients consisting of complex chemical mixtures. Recreating perfumes in this manner is very expensive, unless one has access to the same complex ingredients as the original formulators.

Furthermore the delibrate addition of inert ingredients to obscure the formula makes identification of components difficult. Antique or badly preserved perfumes undergoing this analysis can also be difficult due to the numerous degradation by-products and impurities that may have resulted from breakdown of the odourous compounds. However, these ingredients and compounds can usually be ruled-out or identified using gas chromatograph (GC) smellers, which allow individual chemical components to be identified both through their physical properties and their scent.

History of perfume and perfumery

Perfume:Egyptian scene depicting the preparation of Lily perfume
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Egyptian scene depicting the preparation of Lily perfume

The word perfume used today derives from the Latin "per fume", meaning through smoke. Perfumery, or the art of making perfumes, began in ancient Egypt but was developed and further refined by the Romans and the Arabs. Although perfume and perfumery also existed in East Asia, much of its fragrances are Incense based.

Islamic

Islamic cultures contributed significantly in the development of western perfumery in both perfecting the extraction of fragrances through steam distillation and introducing new, raw ingredients. Both of the raw ingredients and distillation technology significantly influenced western perfumery and scientific developments, particularly chemistry.

As traders, Islamic cultures such as the Arabs and Persians had wider access to different spices, herbals, and other fragrance material. In addition to trading them, many of these exotic materials were cultivated by the Muslims such that they can be successfully grown outside of their native climates. Two examples of this include jasmine, which is native to South and Southeast Asia, and various citrus, which are native to East Asia. Both of these ingredients are still highly important in modern perfumery.

In Islamic culture, perfume usage has been documented as far back as the 6th century and its usage is considered a religious duty. The Prophet Muhammad said:

   
Perfume:Perfume
The taking of a bath on Friday is compulsory for every male Muslim who has attained the age of puberty and (also) the cleaning of his teeth with Miswaak (type of twig used as a toothbrush), and the using of perfume if it is available. (Recorded in Sahih Bukhari).
   
Perfume:Perfume

Such rituals gave incentives to scholars to search and develop a cheaper way to produce incenses and in mass production. Thanks to the hard work of two talented chemists: Jabir ibn Hayyan (born 722, Iraq), and al-Kindi (born 801, Iraq) who established the perfume industry. Jabir developed many techniques, including distillation, evaporation and filtration, which enabled the collection of the odour of plants into a vapour that could be collected in the form of water or oil. [5]

Al-Kindi, however, was the real founder of perfume industry as he carried out extensive research and experiments in combining various plants and other sources to produce a variety of scent products. He elaborated a vast number of ‘recipes’ for a wide range of perfumes, cosmetics and pharmaceuticals. His work in the laboratory is reported by a witness who said:

   
Perfume:Perfume
I received the following description, or recipe, from Abu Yusuf Ya'qub b. Ishaq al-Kindi, and I saw him making it and giving it an addition in my presence.
   
Perfume:Perfume

The writer goes on in the same section to speak of the preparation of a perfume called ghaliya, which contained musk, amber and other ingredients; too long to quote here, but which reveals a long list of technical names of drugs and apparatus.

Musk and floral perfumes were brought to Europe in the 11th and 12th centuries from Arabia, through trade with the Islamic world and with the returning Crusaders. Those who traded for these were most often also involved in trade for spices and dyestuffs. There are records of the Pepperers Guild of London, going back to 1179; which show them trading with Muslims in spices, perfume ingredients and dyes.[6]

Western

Knowledge of perfumery came to Europe as early as the 14th century due partially to Muslim influences and knowledge. During the Renaissance period, perfumes were used primarily by royalty and the wealthy to mask body odors resulting from the sanitary practices of the day. Partly due to this patronage, the western perfumery industry was created. By the 18th century, aromatic plants were being grown in the Grasse region of France to provide the growing perfume industry with raw materials. Even today, France remains the centre of the European perfume design and trade.

Perfumers were also known to create poisons; for instance, a French duchess was murdered when a perfume/poison was rubbed into her gloves and was slowly absorbed into her skin. [citation needed]

Health and ethical issues

In some cases, an excessive use of perfumes may cause allergic reactions of the skin. For instance, acetophenone, ethyl acetate and acetone while present in many perfumes, are also known or potential respiratory allergens.

Perfume:Unbalanced scales.svg
The neutrality of this section is disputed.
Please see the discussion on the talk page.

Natural versus synthetic aromatics

Natural musk

Musk was traditionally taken from the male musk deer Moschus moschiferus. This requires the killing of the animal in the process. Although the musk pod is produced only by a young male deer, musk hunters usually did not discriminate between the age and sex of the deers. Due to the high demand of musk and indiscriminate hunting, populations were severely depleted. As a result, the deer is now protected by law and international trade of musk from Moschus moschiferus is prohibited:

   
Perfume:Perfume
Musk deer are protected under national legislation in many countries where they are found. The musk deer populations of Afghanistan, Bhutan, India, Nepal and Pakistan are included in Appendix I of CITES, the Convention on International Trade in Endangered Species of Wild Fauna and Flora. This means that these musk deer and their derivatives are banned from international commercial trade. [1]
   
Perfume:Perfume

Due to the rarity and high price of natural musk, as well as for legal and ethical reasons, it is the policy of many perfume companies to use synthetic musk instead. Numerous synthetic musks of high quality are readily available and approved safe by IFRA. However, many synthetic musks have been found in human fat, mother's milk [2], and the bottom of the Great Lakes [3], .

Preserving perfume

Fragrance compounds in perfumes will denature and break down if improperly stored in the presence of:

Proper preservation of perfumes involve keeping them away from sources of heat and store them where they will not be exposed to light. An open bottle will keep its aroma intact for up to a year, as long as it is full or nearly so, but as the level goes down, the presence oxygen in the air that is contained in the bottle will alter the perfume's smell character, eventually distorting them.[1]

As such perfumes are best preserved when kept in light-tight aluminium bottles or in their original packaging when not in use, and refrigerated at a relatively low temperatures between 3-7 degrees celsius. Although it is difficult to completely remove oxygen from the headspace of a stored flask of fragrance, opting for spray despensers instead of rollers and "open" bottles will minimize oxygen exposure. Sprays also have the advantage of isolating fragrance inside a bottle and preventing it from mixing with dust, skin, and detritus, which will degrade and alter the quality of a perfume.

Lists of perfumes

Famous perfumes classified by year of creation

YearNameCompanyPerfumer
1714 Eau de Cologne Johann Maria Farina Johann Maria Farina (1685-1766)
1872Hammam BouquetPenhaligon's William Henry Penhaligon
1889JickyGuerlainAimé Guerlain
1902Blenheim BouquetPenhaligon'sWilliam Henry Penhaligon
1912L'Heure BleueGuerlainJacques Guerlain
1911English FernPenhaligon'sWilliam Henry Penhaligon
1917ChypreFrançois CotyFrançois Coty
1919MitsoukoGuerlainJacques Guerlain
1919Tabac BlondCaronErnest Daltroff
1921N°5ChanelErnest Beaux
1925ShalimarGuerlainJacques Guerlain
1927ArpègeLanvinAndré Fraysse
1929Soir de ParisBourjoisErnest Beaux
1930Joy Jean PatouHenri Alméras
1932Je ReviensHouse of Worth
1934Pour Un HommeCaronErnest Daltroff
1944BanditRobert PiguetGermaine Cellier
1945FemmeRochasEdmond Roudnitska
1947Vent VertBalmainGermaine Cellier
1948L'Air du tempsNina RicciFrancis Fabron
1956DiorissimoChristian DiorEdmond Roudnitska
1959MonsieurGivenchy
1959CabochardParfums GrèsBernard Chant
1966Eau sauvageChristian DiorEdmond Roudnitska
1969ÔLancômeRobert Gonnon
1973CharlieRevlonHarry A. Cuttler
1976Lily of the Valley Penhaligon's
1976 Violetta Penhaligon's
1976Z-14HalstonArden
1977OpiumYves Saint-LaurentJean-Louis Sieuzac
1978Azzaro Pour HommeAzzaroGérard Anthony, Martin Heiddenreich, Richard Wirtz
1978BluebellPenhaligon's
1978Magie NoireLancômePFW
1979Anaïs AnaïsCacharelRoger Pellegrino
1979IvoireBalmain
1981Nombre NoirShiseidoSerge Lutens, Jean-Yves Leroy
1981GiorgioGiorgio Beverly HillsHarry A. Cuttler
1983ParisYves Saint-LaurentSophia Grojsman
19845 DegreesChanelJacques Polge
1985PoisonChristian DiorJean Guichard
1986Prescriptives CalyxPrescriptivesSophia Grojsman
1987LoulouCacharelJean Guichard
1988EternityCalvin KleinSophia Grojsman
1990TrésorLancômeSophia Grojsman
1992AngelThierry MuglerOlvier Cresp and Yves de Chiris
1993Jean-Paul GaultierJean-Paul GaultierJacques Cavallier
1995CK OneCalvin KleinHarry Fremont and Alberto Morillas
1995Dolce VitaChristian DiorPierre Bourdon and Maurice Roger
1995Le MâleJean-Paul GaultierFrancis Kurkdjian
1996Acqua di Gió Pour HommeGiorgio ArmaniAlberto Morillas
1997EnvyGucciMaurice Roucel
1999No 1Clive Christian
2001Coco MademoiselleChanelJacques Polge
2001NuYves Saint-LaurentJacques Cavallier
2003100% LoveShaping RoomSophia Grojsman
2005ChinatownBond No. 9Aurelien Guichard
2005Rose 31Le LaboDaphne Bugey
2005VertigoVertigo ParfumsCecile Krakower

Celebrity endorsed perfumes

In recent years, celebrities have signed contracts with perfume houses to associate their name with a signature scent, as a self-promotion campaign. The scents are then marketed; the association with the celebrity's name usually being the selling point of the campaign. Such products generally do not have the longevity of classic fragrances.

Celebrity scents

Promotional scents associated with fictional characters

See also

References

  1. ^ a b c Burr, Chandler (2003). The Emperor of Scent: A Story of Perfume, Obsession, and the Last Mystery of the Senses. New York: Random House. ISBN 0-375-50797-3.
  2. ^ a b c Fortineau, Anne-Dominique (2004). "Chemistry Perfumes Your Daily Life". Journal of Chemical Education.81(1)
  3. ^ Edwards, Michael (2006). "Fragrances of the World 2006". Crescent House Publishing. ISBN 0-9756097-1-8
  4. ^ Camps, Arcadi Boix (2000). "Perfumery Techniques in Evolution". Allured Pub Corp. ISBN 0-931710-72-3
  5. ^ Levey, Martin (1973), "Early Arabic Pharmacology", E.J. Brill: Leiden, ISBN 90-04-03796-9
  6. ^ Dunlop, D.M. (1975), "Arab Civilization", Librairie du Liban

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